NF EN ISO 16017-2

NF EN ISO 16017-2

October 2003
Standard Current

Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 2 : diffusive sampling

ISO 16017-2:2003 gives general guidance for the sampling and analysis of volatile organic compounds (VOCs) in air. It is applicable to indoor, ambient and workplace air. ISO 16017-2:2003 is applicable to a wide range of VOCs, including hydrocarbons, halogenated hydrocarbons, ester, glycol ethers, ketones and alcohols. A number of sorbents are recommended for the sampling of these VOCs, each sorbent having a different range of applicability. Very polar compounds generally require derivatisation; very low boiling compounds are only partially retained by the sorbents and can only be estimated qualitatively. Semi-volatile compounds are fully retained by the sorbents, but may only be partially recovered. ISO 16017-2:2003 is applicable to the measurement of airborne vapours of VOCs in a concentration range of approximately 0,002 mg/m3 to 100 mg/m3 individual organic for an exposure time of 8 h, or 0,3 g/m3 to 300 g/m3 individual organic for an exposure time of four weeks. The upper limit of the useful range is set by the sorptive capacity of the sorbent used and by the linear dynamic range of the gas chromatograph column and detector or by the sample splitting capability of the analytical instrumentation used. The lower limit of the useful range depends on the noise level of the detector and on blank levels of analyte and/or interfering artefacts on the sorbent tubes. Artefacts are typically sub-nanogram for well-conditioned Tenax GR and carbonaceous sorbents, carbonized molecular sieves and pure charcoals; at low nanogram levels for Tenax TA and at 5 ng to 50 ng levels for other porous polymers.

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Main informations

Collections

National standards and national normative documents

Publication date

October 2003

Number of pages

45 p.

Reference

NF EN ISO 16017-2

ICS Codes

13.040.01   Air quality in general

Classification index

X43-510-2

Print number

1 - 11/12/2003

International kinship

European kinship

EN ISO 16017-2:2003
Sumary
Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 2 : diffusive sampling

ISO 16017-2:2003 gives general guidance for the sampling and analysis of volatile organic compounds (VOCs) in air. It is applicable to indoor, ambient and workplace air.

ISO 16017-2:2003 is applicable to a wide range of VOCs, including hydrocarbons, halogenated hydrocarbons, ester, glycol ethers, ketones and alcohols. A number of sorbents are recommended for the sampling of these VOCs, each sorbent having a different range of applicability. Very polar compounds generally require derivatisation; very low boiling compounds are only partially retained by the sorbents and can only be estimated qualitatively. Semi-volatile compounds are fully retained by the sorbents, but may only be partially recovered.

ISO 16017-2:2003 is applicable to the measurement of airborne vapours of VOCs in a concentration range of approximately 0,002 mg/m3 to 100 mg/m3 individual organic for an exposure time of 8 h, or 0,3 g/m3 to 300 g/m3 individual organic for an exposure time of four weeks.

The upper limit of the useful range is set by the sorptive capacity of the sorbent used and by the linear dynamic range of the gas chromatograph column and detector or by the sample splitting capability of the analytical instrumentation used. The lower limit of the useful range depends on the noise level of the detector and on blank levels of analyte and/or interfering artefacts on the sorbent tubes. Artefacts are typically sub-nanogram for well-conditioned Tenax GR and carbonaceous sorbents, carbonized molecular sieves and pure charcoals; at low nanogram levels for Tenax TA and at 5 ng to 50 ng levels for other porous polymers.

Table of contents
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  • Avant-propos
    iv
  • Domaine d'application
  • 2 Références normatives
    2
  • 3 Principe
    2
  • 4 Réactifs et matériaux
    2
  • 5 Appareillage 4
  • 6 Conditionnement du tube d'échantillon
    6
  • 7 Échantillonnage
    6
  • 8 Mode opératoire
    7
  • 8.1 Précautions de sécurité
    l
  • 8.2 Désorption et analyse
    l
  • 8.3 Étalonnage
    9
  • 8.4 Détermination de la concentration de l'échantillon
    9
  • 8.5 Détermination du rendement de désorption
    9
  • 8.6 Étalonnage du débit de prélèvement par diffusion
    10
  • 9 Calculs
    10
  • 9.1 Concentration en masse de l'analyte
    10
  • 9.2 Concentration en volume de l'analyte
    11
  • 9.3 Débits de prélèvement par diffusion
    11
  • 10 Interférences
    11
  • 11 Caractéristiques des performances
    12
  • 12 Rapport d'essai
    12
  • 13 Contrôle de la qualité
    12
  • Annexe A (informative) Principes de fonctionnement de l'échantillonnage par diffusion
    23
  • Annexe B (informative) Description des types d'adsorbant
    29
  • Annexe C (informative) Lignes directrices concernant la sélection des adsorbants
    30
  • Annexe D (informative) Lignes directrices concernant l'utilisation des adsorbants
    32
  • Annexe E (informative) Récapitulatif des données sur l'incertitude globale, la fidélité, l'erreur systématique et le stockage
    34
  • Bibliographie
    36
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