NF ISO 21438-1

NF ISO 21438-1

April 2008
Standard Cancelled

Workplace atmospheres - Determination of inorganic acids by ion chromatography - Part 1 : non-volatile acids (sulphuric acid and phosphoric acid)

ISO 21438-1:2007 specifies a method for the determination of the time-weighted average mass concentration of sulfuric acid and phosphoric acid in workplace air by ion chromatography. The method is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708 and to static (area) sampling. The analytical method is applicable to the determination of masses of 0,005 mg to 2,000 mg of sulfuric acid and phosphoric acid per sample, without dilution. The concentration range of sulfuric acid and phosphoric acid in air for which the measuring procedure is applicable is determined by the sampling method selected by the user. For an air sample of volume 1 m3, the working range is approximately 0,005 mg/m3 to 2,000 mg/m3. The method is not applicable to the determination of sulfur trioxide. The procedure does not allow differentiation between the acids and their corresponding salts if both are present in the air. The procedure does not allow differentiation between phosphoric acid and diphosphorus pentoxide (phosphoric anhydride) if both are present in the workplace.

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Main informations

Collections

National standards and national normative documents

Thematics

Gestion des risques et SST

Publication date

April 2008

Number of pages

38 p.

Reference

NF ISO 21438-1

ICS Codes

13.040.30   Workplace atmospheres

Classification index

X43-211-1

Print number

1 - 02/04/2008

International kinship

Sumary
Workplace atmospheres - Determination of inorganic acids by ion chromatography - Part 1 : non-volatile acids (sulphuric acid and phosphoric acid)

ISO 21438-1:2007 specifies a method for the determination of the time-weighted average mass concentration of sulfuric acid and phosphoric acid in workplace air by ion chromatography.

The method is applicable to the personal sampling of the inhalable fraction of airborne particles, as defined in ISO 7708 and to static (area) sampling.

The analytical method is applicable to the determination of masses of 0,005 mg to 2,000 mg of sulfuric acid and phosphoric acid per sample, without dilution.

The concentration range of sulfuric acid and phosphoric acid in air for which the measuring procedure is applicable is determined by the sampling method selected by the user. For an air sample of volume 1 m3, the working range is approximately 0,005 mg/m3 to 2,000 mg/m3.

The method is not applicable to the determination of sulfur trioxide.

The procedure does not allow differentiation between the acids and their corresponding salts if both are present in the air.

The procedure does not allow differentiation between phosphoric acid and diphosphorus pentoxide (phosphoric anhydride) if both are present in the workplace.

Standard replaced by (1)
NF ISO 21438-1
July 2022
Standard Current
Workplace atmospheres - Determination of inorganic acids by ion chromatography - Part 1 : non-volatile acids (sulfuric acid and phosphoric acid)

<p>This document specifies a method for the determination of the time-weighted average mass concentration of sulfuric acid and phosphoric acid in workplace air by ion chromatography. The anions are detected by conductivity.</p> <p>The method is applicable to the personal sampling of airborne particles, as defined in ISO 7708, and to static (area) sampling.</p> <p>The method does not apply to the determination of sulfur trioxide.</p> <p>The procedure does not differentiate between the acids and their corresponding salts if both are present in the workplace air.</p> <p>The procedure does not differentiate between phosphoric acid and diphosphorus pentoxide (phosphoric anhydride) if both are present in the workplace air.</p>

Table of contents
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  • Avant-propos
    iv
  • Introduction
    v
  • 1 Domaine d'application
    1
  • 2 Références normatives
    1
  • 3 Définitions
    2
  • 3.1 Définitions générales
    2
  • 3.2 Définitions des fractions de taille de particules
    3
  • 3.3 Définitions relatives à l'échantillonnage
    3
  • 3.4 Définitions relatives à l'analyse
    4
  • 3.5 Termes statistiques
    5
  • 4 Principe
    6
  • 5 Exigences
    7
  • 6 Réactifs
    7
  • 7 Appareillage
    9
  • 7.1 Matériel d'échantillonnage
    9
  • 7.2 Appareillage de laboratoire
    11
  • 8 Évaluation de l'exposition professionnelle
    13
  • 8.1 Généralités
    13
  • 8.2 Échantillonnage individuel
    13
  • 8.3 Échantillonnage à point fixe
    13
  • 8.4 Sélection des conditions de mesurage et du mode de mesurage
    13
  • 9 Échantillonnage
    15
  • 9.1 Considérations préliminaires
    15
  • 9.2 Préparation du prélèvement d'échantillons
    17
  • 9.3 Point d'échantillonnage
    17
  • 9.4 Prélèvement des échantillons
    18
  • 9.5 Transport
    18
  • 10 Analyse
    19
  • 10.1 Préparation des solutions d'essai et d'étalonnage
    19
  • 10.2 Analyse instrumentale
    20
  • 10.3 Estimation des limites de détection et de quantification
    21
  • 10.4 Maîtrise de la qualité
    22
  • 10.5 Incertitude de mesure
    23
  • 11 Expression des résultats
    23
  • 12 Performances de la méthode
    24
  • 12.1 Prélèvement et conservation de l'échantillon
    24
  • 12.2 Limites de quantification
    24
  • 12.3 Limites supérieures de la gamme d'analyse
    24
  • 12.4 Biais et fidélité
    24
  • 12.5 Incertitude de l'échantillonnage et de la méthode d'analyse
    24
  • 12.6 Interférences
    25
  • 13 Rapport d'essai
    25
  • 13.1 Procès-verbal de l'essai
    25
  • 13.2 Rapport de laboratoire
    26
  • Annexe A (informative) Correction de température et de pression
    27
  • Bibliographie
    29
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