NF EN ISO 15681-2

NF EN ISO 15681-2

June 2005
Standard Cancelled

Water quality - Determination of orthophosphate and total phosphorus by flow analysis (FIA and CFA) - Part 2 : method by continuous flow analysis (CFA)

ISO 15681-2:2003 specifies CFA methods for the determination of orthophosphate in the mass concentration range from 0,01 mg/l to 1,00 mg/l P, and total phosphorus in the mass concentration range from 0,10 mg/l to 10,0 mg/l P. The method includes the digestion of organic phosphorus compounds and the hydrolysis of inorganic polyphosphate compounds, performed either manually as described in ISO 6878 or with an integrated UV digestion and hydrolysis unit. ISO 15681-2:2003 is applicable to various types of water (such as ground, drinking, surface, leachate and waste water). The range of application may be changed by varying the operating conditions. This method is also applicable to the analysis of seawater, but with changes in sensitivity, by adaptation of the carrier and calibration solutions to the salinity of the samples.

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Main informations

Collections

National standards and national normative documents

Publication date

June 2005

Number of pages

27 p.

Reference

NF EN ISO 15681-2

ICS Codes

13.060.50   Examination of water for chemical substances

Classification index

T90-083-2

Print number

1 - 28/12/2007

International kinship

European kinship

EN ISO 15681-2:2004
Sumary
Water quality - Determination of orthophosphate and total phosphorus by flow analysis (FIA and CFA) - Part 2 : method by continuous flow analysis (CFA)

ISO 15681-2:2003 specifies CFA methods for the determination of orthophosphate in the mass concentration range from 0,01 mg/l to 1,00 mg/l P, and total phosphorus in the mass concentration range from 0,10 mg/l to 10,0 mg/l P. The method includes the digestion of organic phosphorus compounds and the hydrolysis of inorganic polyphosphate compounds, performed either manually as described in ISO 6878 or with an integrated UV digestion and hydrolysis unit.

ISO 15681-2:2003 is applicable to various types of water (such as ground, drinking, surface, leachate and waste water). The range of application may be changed by varying the operating conditions.

This method is also applicable to the analysis of seawater, but with changes in sensitivity, by adaptation of the carrier and calibration solutions to the salinity of the samples.

Standard replaced by (1)
NF EN ISO 15681-2
December 2018
Standard Current
Water quality - Determination of orthophosphate and total phosphorus contents by flow analysis (FIA and CFA) - Part 2 : method by continuous flow analysis (CFA)

<p>This document specifies continuous flow analysis (CFA) methods for the determination of orthophosphate in the mass concentration range from 0,01 mg/l to 1,00 mg/l P, and total phosphorus in the mass concentration range from 0,10 mg/l to 10,0 mg/l P. The method includes the digestion of organic phosphorus compounds and the hydrolysis of inorganic polyphosphate compounds, performed either manually, as described in ISO 6878 and in References [4], [5] and [7], or with an integrated ultraviolet (UV) digestion and hydrolysis unit.</p> <p>This document is applicable to various types of water, such as ground, drinking, surface, leachate and waste water. The range of application can be changed by varying the operating conditions.</p> <p>This method is also applicable to the analysis of seawater, but with changes in sensitivity by adapting the carrier and calibration solutions to the salinity of the samples. </p> <p>It is also applicable to analysis using 10 mm to 50 mm cuvettes depending on the desired range. For extreme sensitivity, 250 mm and 500 mm long way capillary flow cells (LCFCs) can be used. However, the method is not validated for these two uses. Changes in sensitivity and calibration solutions could be required.</p> <p>Annex A provides examples of a CFA system. Annex B gives performance data from interlaboratory trials. Annex C gives information of determining orthophosphate-P and total-P by CFA and tin(II) chloride reduction.</p>

Table of contents
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  • Avant-propos
    iv
  • Introduction
    v
  • 1 Domaine d'application
    1
  • 2 Références normatives
    1
  • 3 Interférences
    2
  • 3.1 Interférences générales
    2
  • 3.2 Interférences sur le dosage du phosphore total
    2
  • 4 Principe
    3
  • 4.1 Dosage des orthophosphates
    3
  • 4.2 Phosphore total avec digestion manuelle
    3
  • 4.3 Phosphore total avec digestion UV intégrée et hydrolyse
    3
  • 5 Réactifs
    3
  • 6 Appareillage
    7
  • 6.1 Analyse en flux continu (CFA)
    7
  • 6.2 Appareillage supplémentaire
    8
  • 6.3 Appareillage supplémentaire pour le dosage du phosphore total après digestion intégrée
    8
  • 7 Échantillonnage et préparation de l'échantillon
    8
  • 8 Mode opératoire
    9
  • 8.1 Préparation pour l'analyse
    9
  • 8.2 Contrôles des performances de l'instrument
    9
  • 8.3 Contrôle du réactif à blanc
    9
  • 8.4 Étalonnage
    9
  • 8.5 Vérification de la digestion UV et de l'hydrolyse pour le dosage du phosphore total
    10
  • 8.6 Mesurage
    10
  • 8.7 Arrêt du dispositif
    10
  • 9 Calcul des résultats
    11
  • 10 Expression des résultats
    11
  • 11 Rapport d'essai
    11
  • Annexe A (informative) Exemples de dispositif CFA
    12
  • Annexe B (informative) Fidélité et exactitude
    14
  • Annexe C (informative) Dosage des orthophosphates-P et du phosphore total par CFA, avec réduction par le chlorure d'étain(II)
    16
  • Bibliographie
    17
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