NF EN ISO 11890-2

NF EN ISO 11890-2

June 2013
Standard Cancelled

Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 2 : gas-chromatographic method

ISO 11890-2:2013 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products.It specifies a method for the determination of the volatile organic compound (VOC) content of paints, varnishes and their raw materials. This part is preferred if the expected VOC content is greater than 0,1 % by mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the less complicated method given in ISO 11890‑1 may be used.This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations.

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Main informations

Collections

National standards and national normative documents

Publication date

June 2013

Number of pages

27 p.

Reference

NF EN ISO 11890-2

ICS Codes

87.040   Paints and varnishes

Classification index

T30-407-2

Print number

1 - 21/05/2013

International kinship

European kinship

EN ISO 11890-2:2013
Sumary
Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 2 : gas-chromatographic method

ISO 11890-2:2013 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products.

It specifies a method for the determination of the volatile organic compound (VOC) content of paints, varnishes and their raw materials. This part is preferred if the expected VOC content is greater than 0,1 % by mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the less complicated method given in ISO 11890‑1 may be used.

This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations.

Replaced standards (1)
NF EN ISO 11890-2
February 2007
Standard Cancelled
Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 2 : gas-chromatographic method

ISO 11890-2:2006 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products. It specifies a method for the determination of the volatile organic compound (VOC) content of paints, varnishes and their raw materials. ISO 11890-2 is preferred if the expected VOC content is greater than 0,1 % by mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the less complicated method given in ISO 11890-1 may be used. This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations.

Standard replaced by (1)
NF EN ISO 11890-2
July 2020
Standard Current
Paints and varnishes - Determination of volatile organic compounds(VOC) and/or semi volatile organic compounds (SVOC) content - Part 2 : gas-chromatographic method

This document is applicable for the determination of VOC and SVOC with an expected VOC and/or SVOC content greater than 0,01 % by mass up to 100 % by mass. The method given in ISO 11890-1 is used when the VOC is greater than 15 % by mass. This document (method ISO 11890-2) applies when the system contains VOC and SVOC as the VOC result of ISO 11890-1 can be influenced by the SVOC. For VOC content smaller than 0,1 %, the head space method described in ISO 17895 is used as an alternative. ISO 11890-1 and ISO 17895 cannot be used for the determination of the SVOC content. NOTE 1 Some ingredients of coating materials and their raw materials can decompose during analysis and cause artificial VOC and/or SVOC signals. When determining VOC and/or SVOC for coating materials and their raw materials, these signals are artefacts of the method and are not taken into account (examples are given in Annex B). This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations. The method defined in this document is not applicable for determination of water content. NOTE 2 If organic acids or bases and their corresponding salts are present in the coating material or its raw materials, the amount that is quantified by this method might not be accurate due to a change in the acid or base equilibrium.

Table of contents
  • Avant-propos
    v
  • 1 Domaine d'application
    1
  • 2 Références normatives
    1
  • 3 Termes et définitions
    1
  • 4 Principe
    2
  • 5 Informations supplémentaires exigées
    2
  • 6 Appareillage
    3
  • 6.1 Chromatographe en phase gazeuse
    3
  • 6.2 Système d'injection de l'échantillon
    3
  • 6.3 Étuve
    3
  • 6.4 Détecteur
    4
  • 6.5 Colonne capillaire
    4
  • 6.6 Matériel d'analyse qualitative
    4
  • 6.7 Seringue d'injection
    4
  • 6.8 Enregistreur de diagramme
    4
  • 6.9 Intégrateur
    5
  • 6.10 Flacons pour échantillon
    5
  • 6.11 Filtres à gaz
    5
  • 6.12 Gaz
    5
  • 7 Réactifs
    5
  • 7.1 Étalon interne
    5
  • 7.2 Composés d'étalonnage
    5
  • 7.3 Solvant de dilution
    5
  • 7.4 Composé marqueur
    6
  • 8 Échantillonnage
    6
  • 9 Mode opératoire
    6
  • 9.1 Masse volumique
    6
  • 9.2 Teneur en eau
    6
  • 9.3 Conditions de chromatographie en phase gazeuse
    6
  • 9.4 Analyse qualitative du produit
    6
  • 9.5 Étalonnage
    7
  • 9.6 Préparation des échantillons
    7
  • 9.7 Détermination quantitative de la teneur en composés
    7
  • 10 Calculs
    8
  • 10.1 Généralités
    8
  • 10.2 Méthode 1: Teneur en COV, en pourcentage en masse, du produit "prêt à l'emploi"
    8
  • 10.3 Méthode 2: Teneur en COV en grammes par litre, du produit "prêt à l'emploi"
    9
  • 10.4 Méthode 3: Teneur en COV en grammes par litre, du produit "prêt à l'emploi" moins l'eau
    9
  • 10.5 Méthode 4: Teneur en COV en grammes par litre, du produit "prêt à l'emploi" moins l'eau et moins les composés exempts (requise uniquement lorsqu'une législation nationale s'applique)
    9
  • 11 Expression des résultats
    10
  • 12 Fidélité
    10
  • 12.1 Généralités
    10
  • 12.2 Limite de répétabilité, r
    10
  • 12.3 Limite de reproductibilité, R
    11
  • 13 Rapport d'essai
    11
  • Annexe A (normative) Informations supplémentaires exigées
    12
  • Annexe B (informative) Exemples de conditions de chromatographie en phase gazeuse
    13
  • Bibliographie
    17
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