NF EN ISO 11890-2
Paints and varnishes - Determination of volatile organic compounds(VOC) and/or semi volatile organic compounds (SVOC) content - Part 2 : gas-chromatographic method
This document is applicable for the determination of VOC and SVOC with an expected VOC and/or SVOC content greater than 0,01 % by mass up to 100 % by mass.The method given in ISO 11890-1 is used when the VOC is greater than 15 % by mass. This document (method ISO 11890-2) applies when the system contains VOC and SVOC as the VOC result of ISO 11890-1 can be influenced by the SVOC. For VOC content smaller than 0,1 %, the head space method described in ISO 17895 is used as an alternative. ISO 11890-1 and ISO 17895 cannot be used for the determination of the SVOC content.NOTE 1 Some ingredients of coating materials and their raw materials can decompose during analysis and cause artificial VOC and/or SVOC signals. When determining VOC and/or SVOC for coating materials and their raw materials, these signals are artefacts of the method and are not taken into account (examples are given in Annex B).This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations. The method defined in this document is not applicable for determination of water content.NOTE 2 If organic acids or bases and their corresponding salts are present in the coating material or its raw materials, the amount that is quantified by this method might not be accurate due to a change in the acid or base equilibrium.
This document is applicable for the determination of VOC and SVOC with an expected VOC and/or SVOC content greater than 0,01 % by mass up to 100 % by mass.
The method given in ISO 11890-1 is used when the VOC is greater than 15 % by mass. This document (method ISO 11890-2) applies when the system contains VOC and SVOC as the VOC result of ISO 11890-1 can be influenced by the SVOC. For VOC content smaller than 0,1 %, the head space method described in ISO 17895 is used as an alternative. ISO 11890-1 and ISO 17895 cannot be used for the determination of the SVOC content.
NOTE 1 Some ingredients of coating materials and their raw materials can decompose during analysis and cause artificial VOC and/or SVOC signals. When determining VOC and/or SVOC for coating materials and their raw materials, these signals are artefacts of the method and are not taken into account (examples are given in Annex B).
This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations. The method defined in this document is not applicable for determination of water content.
NOTE 2 If organic acids or bases and their corresponding salts are present in the coating material or its raw materials, the amount that is quantified by this method might not be accurate due to a change in the acid or base equilibrium.
ISO 11890-2:2013 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products. It specifies a method for the determination of the volatile organic compound (VOC) content of paints, varnishes and their raw materials. This part is preferred if the expected VOC content is greater than 0,1 % by mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the less complicated method given in ISO 11890‑1 may be used. This method assumes that the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations.
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1 Domaine d'application
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2 Références normatives
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3 Termes et définitions
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4 Principe
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5 Informations requises
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6 Appareillage
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7 Réactifs
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8 Mode opératoire
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9 Analyse des données
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10 Détermination quantitative de la teneur en composés
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11 Calcul de la teneur en COV et en COSV
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12 Évaluation des données et calcul du résultat final
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13 Fidélité
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14 Rapport d'essai
- Annexe A Liste non exhaustive des composés COV, COSV et CONV
- Annexe B Informations sur les produits thermiquement instables
- Annexe C Exemples de conditions pour la méthode CG
- Annexe D Résultats de l'essai interlaboratoires pour la détermination des données de fidélité
- Bibliographie
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